If they are running in Dual Channel, i think it will say when the computer boots up. I've got a Soltek 75LFRN2-L mobo, and have 2 sticks of PC2700 ram running in dual channel (they are both 256). When the computer boots up, it tells me Dual Channel Activated at 166 MHZ, it is probably a little bit different for other motherboards though.
And the RAM doesn't have to be exactly the same to run in dual channel mode, I've seen it work on 2 sticks of different PC2100 ram, but they were both still 256, I am unaware about it working with two different size sticks.